Photodynamic Control of the Chain Length in Supramolecular Polymers: Switching an Intercalator into a Chain Capper
نویسندگان
چکیده
منابع مشابه
Supramolecular polymers: Chain growth in control.
Supramolecular polymers are a class of materials characterized by a repetition of monomer units held together by non-covalent forces such as metal coordination, π–π interactions and hydrogen bonding1–4. Compared with their covalent counterparts the unique properties of these polymers have attracted considerable attention, for instance, the self-healing ability that arises from the thermodynamic...
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Supramolecular polymers are linear chains of low molar mass monomers held together by reversible and directional non-covalent interactions, which can form gels or highly viscous solutions if the self-assembled chains are sufficiently long and rigid. The viscosity of these solutions can be controlled by adding monofunctional compounds, which interact with the chain extremities: chain stoppers. W...
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15 صفحه اولChain length dependent alkane/β-cyclodextrin nonamphiphilic supramolecular building blocks.
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2020
ISSN: 0002-7863,1520-5126
DOI: 10.1021/jacs.0c00858